e
H
F.
M
,bl, it immerli1tdl' noll's : the ("Irh"r
a~in~
as a nux
tu it. !\11\'"r tltu, "uitt¡\ lI'ith (ulphur (orms
.1
ma(s tI,.t
""'Y be rm, i, h
¡\f
m.llt ;¡I.I~,
an,1 h"th u"Mly tlt" eo-
1,)ul a",1n.nlil!. """ ,.f
k;¡tI,
If this fulrhu,ated
lilv~r
~l'
k.1"
a 10uC tlln" In fuli"u, aud
10
a creat degrec o(
1\(',11 , ,h" li,ll'ltur 1I,,,s nlT aod
I~al'es
thelilrer purc, Jlut
ir the fulphur he el',lpOr,lteJ by a violeot heat, it carries
011'
IVith it pm of the lilver.
Sil.er'lOiles anu
mix~s
I'erfdlly with gold in fufioo.
The 111'0 met.t1s thus mixeu form
a
eompound IVith pro–
perites r.trt:tkJo!: of both.
~I etallurglll~
h,lI'e hithmo fought in vain fOr a per–
fe~lI)'
guo.l dr..1 e,lry method of kp.lratiog thefe til'O
01:–
Jals by the ':')
'lO")
only: (T his term is ufcJ tO fignily
.11
ul'~r.t!"'::-
pel
fUllncd
by fUlioo :) but they Me eonve–
niend, eoou·' I pmeJ by the
II/újl
'lila).
that IS, by aeid
C"lvents, This method IS foundeu on the above·men·
t1nn~d
rrorenies of gn!'1and lilm
~'ith
refpeél
10
acids.
lt
h.thbetn Ihell'o, tI,"t
oq""
I'<,~j¡
ollly
11
ill u;Ir.,lve
t t,ld; that fi lver, on the e"nmry, is nut fol ubk by
/J–
q '/"
r,:~Í1,
ard that its pl urer
f~ll'ent
is the,aeid of nitre:
C"nfe~uentl\',
II hen gold ,\nd I,h er are nll xed tngether,
ir thc ellnlpoünd m ..fs be put into
(/q""¡orlil,
this aeiu
will
t"k~
up all the fil\'er, ",ithom dlll'ohing a p' lIidc uf
the
~,,¡'I. ~,t.i( h
will thereforc rem.,in rure ; . nd
by
tft"
nI~l"S th~
ddi,ed
I;'p" r~tio"
is
dr~lIed.
This O1Clhod,
'hieh is en Hmnn!y made ufe of by goldfmiths and in
O1,nI' , is " Iietl Ihe
parling
~lfa) .
h
I~
p\.un, that If
oql/fl
"gil
w~re
employed inlle,ld of
07"" ¡',rIÍJ ,
t h~
fep.tration \Vould be equally elTeéled;
an.!
Ihat the only lhfi'crenee
bet\ve~n
thil procefs
~nd
Ihe
f.¡: nl:r 1I0uld elllllifl in this, thal oow the gol" would he
olnol"d, anc! the fil\'er remain pureo But theoperatlon
by
"q'" ¡"Iil
is preferablc; beeaufe
"qu" "gil
does
t"ke up a liltle,filrer, whereas
"qua [orlÍJ
hath nOt the
le,11I dLél on go!d.
.
It
mufl b: ,oliCemd, tIlat when gold and film are
mixed together in equal pam, they eannot be poned by
the rolear" of
a7uo¡mi!.
1'0
eoable the
"qll" /" Ii.
tO
aél duly on the fi
l.er, tbis met.1O1ull be, al leafl. in a
triple prcpol tioo 'o Ihe
g~ld.
If it be in a lefs propar,
tion, you mufl eitber employ
"qua rtgÍJ
to make the fe–
p"ration, or, if you prefer the ufe of
oqua ¡ _rlÍ!,
mell
themmlline mals, and add as much fi l,er as is necefr. ry
10
make up the proponionabOIe·meotioned: And benee
this ploeefs is e"lIed
qu"rlalion,
TIIlS eff:él, whie!. i, pretty fingular, probablyarifes
from heoce. thal whenthe gnld cxeecdl, or el'cn equals
the film in quantity, the pans of both bting intimm ly
uniccd, the former
~rc
cap"bleof coating OVlr the lantr,
. od
cov=rill~
thcm fo
~s
tOdtftnd ,hem from the
~élion
uf the
oqua¡orlll;
",llIeh is not thc cafe when there is
Ihnee as OIuch fil'tr
~'gn:J.
'111~re
is one thingmure 'o
~e
taken no ice of with re·
gHd
10
tllI! procef,; "hid, ", that perfdlly pure
"q""
¡"til
is wdy
I~
be met wi,h, fOI two re..fon':
FIlIt,
it
's dillieuh in matinn it ... holly
10
plevenl thenfingof the
Oled'umcmployed tO difengaJc the nllrOUSaeid
i
,hat is,
a
hule o'f the vitrio!ic aCOlI "'111
mi~
with the vapours of
th,
"qua forlh :
econdly, unlefs the fahpetre be . er)'
,"ell pJli5 d, it \ViII
a1"",p
huId fome fmall ponion of
s
T
R
y,
fed.h, Ihe aeid of w!.ieh, we knnw, is very reacfily ret
luofe by the l'itrioli, ncid, and
c~nf~ql1cntly
riftl
to~':Iher with the ".lpOUr! of the
aq/l" [ortÍ!,
It is ea(y 10
ree, that
"q"(/ ¡"rlÍ!,
nlixcd either ",itn Ihe one or the
other, is not proper fur the paning procefs; heeallfe, as
has jull becn f.1id, Ihe vi triolic and the m.rrtnc ,Icid e–
qllally prccipitate fi lm diflolved in the nitrOIlS acid; by
which OIedns, whclI they are unitetl IVitlt that
aci~,
they
wcaken its
~l1i"n
"l'0n the li lver, and I"nder the ,!t¡folll–
tion. Add, that
"quII ¡.rlil
adultera,ell wllh a miXtlll'C
of fpi, it of I, h beetlnlc' an
"qll '
TtglJ ,
aod eoofeqllently
is rendered "pahle "f Ihlr.,h'lnA guld, In proponiun :Il
its aélion upon film is diminilh.,1,
lo order
10
rcm~dy
this inconvenienee, and f,ee
aqlla
¡o"ÍJ
f,tlm the !'II, ioli
o,
marinc .cid with ",hich it i!
tainted, filve, mul! be dinol" ed therein : By degrccs, a,
the mml difrolve<, thore hetcrogeneons acids I. y hold
of il.
~nJ
preeipiwe "ilh it m the ft" mof a nhlle pow–
der,
a~
IVe obfen'e" bdo,e. Thls preeipiwe
bein~
IVhl/lly fallen, the liqllor grows citar
i
aftcr IVhieh, if it
oc
tilllod elpable or ditrolving morc fill'er, without tllrn–
ing mill:y,
It
nlay be depended on as a perfeétly pure
a·
q//II
¡_rlÍ!.
Then filtre
11,
dilloh'c more tilver In it. as
IlIng .IS il \ViII t"ke up any, nnd you will hal'e a fulution
01"
lil,er in a very purc
aqlla [ouÍ!.
l1y OIe,lOS of thiJ
folution otay other
eqlla ¡"Iil
be punfild : for, pour
a
((W drops the,eof 1010 a \'ery iOlpure
"V/laflrlÍ!,
anJ
iOlOlediatdy Ihe "i,riolic
or
marineacid. with \Vhieh tha¡
"qlla ¡orlÍ!
is eontaminated, IV,II join the fi lm and f, 1I
therewith
10
the boltom. Whcn Ihe fulution of filver
prepa,ed as abol'e dacs nut in the leall afr,'él ,he mnfra–
renel'
01"
the
' V"O [orlil ,
it is then rery pure, and nt
for the purpores or quartalion.
T his opcwioo of pUlifylOg
0v"a¡orlil
by a folution
of filver is ealled the
pm ipilll/" n
.¡
nqllo [orlll ;
and
"V/lOj'rtil
thus punlicJ i, called
pffCipi/ald aqua
[ol'lil.
\Vhco film is difrol\'ed in
"VU1
(orlil
it mal' be fepa–
rateJ therefrom. as ha, been fllCWD, by abforbeot
ean~
and 6xeJ ,Ikalts.
o¡
e
o
p
r
E l.
Or
all the imperfell mcral!, eopper comes the nearrll
to gol.! anu r.lveL lts na'ur.11colour is a deep.red
Y
ti·
10IV.
lt
refins a very violent degree of 6re (or a con(¡–
derable ,iOle ; but loling
liS
phloglnon at lan, it chang.s
itl menll,ne fOrol (ur thal of
a
"Ix, or apure rcdd,O,
m,h. Tltis e,lx is hardly, if at al1, redUCIble to glaf"
",ithout the addilion 01' fOOleth,ng
\O
promote '" rufion ;
a11 that the fi<rcdl hcat can do berng only tOrender
It
roft. Corp' r,
even
",hile it retains in meta/hne form,
and il I·ery pure, requtrcs a confiderable degree of fire tO
meh it, and does not begin to nliw till lung after it il
red·ho\. When io fufion, It communiuteJ a grcentlh
eolour tOthe flame of thc coals.
TI.ismetal is toferror 10 filfe r in poin of ltmity ;
nor is in du8illly fo grw. ,houel, it be pr ry confider–
able: Hut, on the othrr hand, it
e~ctft"
that mml in
Iwdnefs.
It
unites read,ly ..lrh gold and filver: nor
docs it ereatly lerren thm beauty ..ben added tO themin
a
fmall quantity: ay, '1nen procures th:m fum: . d-
vaDt~gel
;