7°
e
H
E
M
m th in thcir comporttion; or, laaly, they difrer on ac·
count of fome adtlitional principies, which not being como
bined
~ith
thcm in fll/licient
9u~ntity
lOhinder their Ca·
linc properties from appca ri"g, permit them to rClain the
name of (,t1ts, though
lh~y rtno~r
lhem I'ery different
fromthe Gmpldl C,line fubflances.
It
is eafy to infer from whal has becn faiJ nf f.!t s in
general, that Comeof them mun be more, rome
IcCs.
lixed
or I'olatile than others, and fome more, fOll1e IcCs, dif·
poCed
10
unite with water, with eanh, or with particular
rons of eml,. aecordillg 10 lhe nalure or the proporti6h
of their principlcs.
Refore
\Ve
praceed further, it is proper jun 10 mention
lhe principal reaCons which induce us to think lhal every
Caline fublbnce is aauallya combination of earthand wa·
ler, as \Ve Cupporeo at our entering 00 this rubjea. The
r,rn is, the conformilYf.!ts havewith earth and waler, or
rhe properties lhey polfcfs in common with both. Of
thefe properties \Ve OJaIl treat fllll y, as occaGon offers 10
conGder lhem, in examining lhe feveral rons of Calrs
T ho fecond is, lbal all f,lts may be aaually refolved in·
to
earth anO water by fundry proceO'cs; particularly by
repe,lled difiolution in waler, eupor:uion, deGccation,
and calcinalion Indeed lhe chemills have nOl yet been
able 10 produce a faline Cubllance by combining earth and
water togclher. T his favours a fufpicion, lhat befides
theCe 1100 lhere is fomeolher principie in the compofition
of f.,lts which eCcapes oor refearehes, becaufe \Ve cannat
preren'e il when we decampare lhem: bUl it is fufficient
ta our purroCe, that water and eanh are demaollrably a·
manglllhe real principies af falinc Cubllances, and that
no experiment hath ever fhewn
liS
any alher,
o¡
A
e
t
D
s,
T H! Gmplell faline fubllance is that cal,led an
ocid,
on
accauOl af ilS lane, which is like that af verjuice,
Corre!,
,'ineg.r, and ather Cour things. whieh far the fame rea·
fon >re alCa called acids. By lhis peculiar talle >re acids
chieOy knawn, They have mOreaver the praperty of
lurning . lIlhe blue and violel colaurs of
veger~bles
red,
which dillinguifhes them fram all ather fa!ts.
The form under whieh acids moll commonlyappear,
js lhal of a tranfparent liquor; lhough Calidily is rather
lhei r nalural lIate. This is awing la lheir aflinilYwith
waler ; which is fa greal, lhal, when they cantain but
jull a, much of il as is nmfrary ta conllitule them Calrs,
aod c1nCc9uently have a Colid form, lhey rapidly llOite
lherewith lhe momenl lhey come iota canlaa Wilh it:
andas the air js always loaded \Vith maillure and aqueaus
'apollrs, its cantatl alane is Cufficienl ta liquify them ;
bmufe they uuite with its humidity, imbibe il greedily,
and by thal means becomefluid.
W~
thmfare fay, lhey
attraa the maillureaf lheair. This change af a Calt
frama Colid ta
a
fluid lIalc, by the fole contaa af Ihe
air, is alfo eallet!
drli7l1illlll:
Ca
lhat when a fall changes
in this manner frama folid inla
a
Ruid farm, il is faid la
run
pu "-liqlli,,",.
Acids being the fimplell fpecil! af
f.line bodies,
th.iraflinities \Vith d,frerenl fubfiances are
IIronger than thaCe of any ather fon of falt with rhe (Jme
{ubfianecs; \Vhieh is agreeable
tu
OUt
faunh prapafitian
taoceroing
aJliruties.
s
T
Il.
Y.
Aeids in general have a grcal affinity with Farths:
thal with which they moll readily unitc is th. unvitrifi·
able eanh ta whieh lOe gave the nameof ablorbent carth.
They feemnal
10
aa at allupan "i"ifiable carrlts, fucl.
as fand; nor yet upan Come alher kinds of calths, at
leallwhile theyare in their natural lIate.
ye¡
th~
na·
ture of th& earths may be in Come medlure changcd, by
making them red hm in lhe fire, aO(I thell qllenching
themCutldellly in caId water: for by repeating this oltcu
theyare brallr,ht nearer 10 the n:lture
01
abCarbenr earrhs,
and rendmo carable of uniting with :Lcicls.
Whenan aeid liquor is mixetl \Vith an abCal'bent eanh,
for inllance with chalk, thefe
t \Va
lubllances inll"ntly
rUnl inlo union \Vith fa much impetuoGty, that a great e·
bullitian is immediatcly praJue-J, 3tt<r.d¡·cl wirh conGo
der, ble hifiing, he,lt , and vapours, which rife the very
inflant af their canjunaian.
.
From the cambinatian of an acid \Vith an ahCarbent
emh rhere ariCes a new compound, which Come
chemil\~
have called
.fal
f"!f"lll;
becauCe the acid by unlting with
the earrh lafes its faur tafle, antl acquires anolher not
unlike that of the cammon Cea·Iall ured in aur
kltch~ns
;
yet varying aecarding ta the difrcrcnt forrs af aeiJs and
earths eambined tagcther. The ami al the fame lime
10Ces ltl praperty al' turning blueor vi"lel regel.bles red.
If we inquire \Vhat is·beeome af its prapenGly ta unite
\Vith water, we fhall find thal the eanh, which of itfelf
is nOl faluble in water, halh by its union \Vith the acid
acquired a facility af dirTalving therein;
Co
that oor
fal
fa!f1l1ll
is Caluble in water. !lul, on theather hand, the
acid hath. by its unian \Vith the earth, Ion part
of
the
aflinily it had Wilh water;
Ca
thal if a
jol
faiju/II
be
dried, and freed af all fuperfluaus hemidity, il will re·
main in thal dry folid form, inllead af amaéling the
maillure of the air and running
ptr
drliqtdum,
as the acid
would do if it were pure and unmixed with eanh
A(id,
have
likewif~
a great affinÍty w¡th the phlogillan.
When we eOOle ta treal of each acid in particular, we
fhall examine the combinatians of each with the pllla–
gillon: they dilTer fa widdy fram one
anot~cr,
and Old'
ny af
lh~m
are fa little knawn, lhal we cannal at preCeol
gi
ve
any general idea of them.
O[
A
L K A L
r s.
ALK.lLtS are faline cambinarions in which there is
¡
greater prupartian of mth than in acids. The princi.
pal arguments that Olay be adduced to prove lhis faa
ar~
theCe: Firll, if they be trw cd in the manner propafed
above for analyfiog (,.Iine fubnanm, lOe abtain framlhem
a much greater quantity af carth than we do fram acid••
Secandly ; bycambioing
cen.inaéids \Vith certain eanhl
lOe ean produce alkalis; or at lean fuch falinc compaunJs
as grcatly rcfemble ahem. Our lhtrd and
1.11
argument
is dl'1l\Vn fram the properties af thafe alkalis whieh,
wl,e~
pUfe and unadulter3ICd wirh ny atiJer prinCipie, have
lefs aflinity with water than uids have, and are alfo
more Gxed, refilling the.utmall force of fire. On Ihil
accouol il is thal they hal'e obtained Ihe litle of
fixtd,
as \vell as ta difiingUlfh tl¡em (rom anather Cpecics af
.Ikali, la be cOIIGdercd hcreafu:r, which is impure and
valatile.
'Thau 11