e
H
E
M
Ihcrc is 'o unfucccbful eon of your opmtion.
lt
is eafy
10 pcreei.e Ihis by the lIink of
g~'¡i~k
which you will
fmd!
~hout
the
furn~ce ; ~nd
morco"er, Ihe
Aam~
tha!
itTu~s
Ihrour.h the apenures
or
the
rcveruer~l()ry
"di
be of a bCAutiful violel enlollr. The
~cid
of fCJ-f"lt
.Iways eivcs this colom tO Ihe Aame of f"eh
m~lIcr,
.,
~re
bUlnt along wilh il. BIlI ir Ihe retnrl break be–
fore the phofphorus hath mane ilS
~prear~nee,
ilS eoo–
tenIS mal' be faved uy throwing
~
numuer of cold bricks
inlo thefire-place, ano upon them a liule watel 10quench
Ihe fire at once." AII Ihefe ufeful obfervations \Ve owe
alfo to M. Ilellot.
The rho1jlhorus here defcribed was firn difeovered by
a eilizcn o( Hamburg
n~med
Brandt, who \Yoiked upon
urine
10
karch o( the rhdofopher's none. Afterwards
two other A<il(ul ehcmifls, who knew nothing more of
the proeefs Ihanthat phofphorlls was oblained fromurine,
or in general from the hllman booy, likewife
end~avour
ed to difcover ir; and eaeh of thern fer.ralely did aau–
ally make Ihe difeovery. TheCe IWO ehemills \Yere
Kunckel and Boylc.
The former perfeacd Ihe diCeol'Cfy, and (ouod out a
mClhad of making it in confiderable quanliries at a time;
whieh oecafioned it 10 be called
Kl/ncJ,I', phofph.,u,.
The olher, \Vho was an Englifh gentleman, had nOI rime
lObring his difeovery ro perCeaion, and eonremed him–
ldf "ilh
lod~ing
a voucher of his having diCcovmd it in
rhe hands of Ihe Cecrelary of rhe Royal Society of
London, who gave him a cerri6cate Ihereor.
" Though Branol, \Yho h.d before rhlS Cold his feeret
to a ehemill
~amed
Krafft , fold it aCterwards ro feveral
orher perColls. and even at a very 1011' rate: and Ihough
Mr Boyle publlfhed the procefs for making il ; yel it is
rMremely
pro~able
thar bOlh of Ihem kepl in rheir own
hands Ihe mancl-key; I mean,
th(
,a,'ieula, lIIanng'–
lI/(IIl
ntc(!la,:,'
ID
1/Ial,
Ih,
.pna/ion
(lIccud:
For till
Kunekel found il our, no olher chemin ever made anf
conf,derable quanlily thereof, except Mr Godrrey Han–
Wil" an Englifh ehcmill, tO IVhom Mr Bo)'le revealed
.he wilole "')'ltery .
" Ana
thus it t'me ro p, fs, that, ,fler Kunckel and
flo)'le died M G'ldfrey Hnnkwilz IVas Ihe 0011' chemill
Ihal conld furpl)' Europe .hereIVith ; on IVhieh accounl
jI is hkeIVife very wdl known by Ihe Dame of
Englijh
r
h
1t
ho
·/IJ."
AlmQil
all l~e
ehemilts eonfider phofphorus as a fub–
flaoee
eo~filting
of Ihe acid of fea·falt combined Wllh
Ihephloginon, in rhe fam e lIIanner as fulphu r confilts
oC
Ihe vitrio!ie aeid combined ,,"Ih rhe phlogillon. This
o?ini~n
is fnuoded on Ihe following principl.,.
r"n. urinc ahnunds wilh fea-falr, and eonlains alfo
a gr.;!t de.1of phloginon: no\Y Ihefe are the in¡:redients
of \lhich rhey coniellure phofporus
10
be eompoled.
Secondl •• phofphorus h" many of the properties 01
fulrhu r; fueh as beinf foluhle in oils; mclting wilh a
gende hm ; bcinr. "ery combunihle; borning IVilhout
any fool;
givin~
a vi,id and bluiOl llame; ,lid laltly,
learing an acid Ilquor \'liten burnl : fenfible proofs Ihal
ir differs froltl fulpbur in
nothin~
but Ibe nature of its
aeid.
s
T
R
Y.
Thirdly, Ihis aeid of phofphoru!, beinfl mixcd with a
folulion of Glver in fpirir of nilre, preeipitate, the fi lm–
and this precipitale is a true
luna
(o,'''.,
whieh appear;
10 be more
vol"i le
even Ihan Ihe common fort. TI",
J" él proVcS more ineonteltably Ihat' the .cId of phofpho–
rus is of Ihe fame narure Will, that of fea-fall .
Fourthly, M. Stahl obferves, thar if fea-falt be
Cdl!
00 Jive eoals, Ihey ionandy burn with grear aaivilY'
rhar chey emil a vivid Baroe, and are mucll fooner eoo:
fum~d
thao if· none ·
oC
thi, fall had touehed them ,'
rhal fea·fall in fubllance, whieh will be,r the violence
of
6re aeonfidlrable lime when fufed in • erueible, wilhou!
funain,ng .ny fenfible diminutioo, yer evaparales ver
y
quickly, .nd is redueed 10 white Rowers, by rhe im–
mediate COnlaa of burniog eoal,; and lanly, rhal Ihe
Bame whieh rifes on this oeeafion is of a blue colour in–
clining to violer, efpeci.lly if ir be oor thruwn direaly
on rhe
co.lsIheOlfe! ves, but kepr io fufion aOlidfl burn–
ing coals. in a elucible fo plmd Ihal the vapour of Ibe
fall may join Wilh the inBamed phlogifloo as il rifes froru
the
e~als.
111&
experimeolsof Mr Sta"!'s prove, rhal the phlo–
gifioo aas opon Ihe acid of fea-falt, eveo while il is eom–
bined lUirh ilS alkaline bafis. The ftame thal 'ppms 00
this oeeafion mal' be confidered as ao imperfea
phofpho~
rus: aod indeeu its colour is exa[l/y Ilke thar of phof–
phorus.
AII the f,as above re/aled e,ince, rhat lhe acid of
phofphorus is akin 10 Ihat of fea-falt;
Of
mher, that ir
is the very falne. BUI thue are other faas whieh prove,
thal this acid undergoes fome ehaoge at Ican, fome pe–
culiar prepmlion, before il enlCl> inlo the
eOOlp~fitjon
o( a trne pholphorus; an,l th. I, wheo eXlrielleu Ihere–
from by burmng, it is Ilor apure acid 01fea-f,It, bur il
fii/l
ad~llerated
\Vi lb a mixlure of fome uther fubndnce ,
whien lOakes ir confio: rably differenl írom thar aeld.
For Ihefe obfemrioos we are obligtd 10 M. Marggraff.
111. Marggraff halh alfo publifhed a procef, fur ma–
kiog phofphorus, and atTures us, Ihat by means thereof
we lIlay obrain in lefs limr, IVith I¿fs hcal, Ids Irouble,
anO
Us
cxpellee, a greater quanlily of phofphorus th'Q
by
~oy
otber melhO<!. His operarion is Ihis :
He take, tWO pounds of fal ammoniac io powder,
whieh he mixcs accuratcIy wilh four pounds of mimurn,
Thismlxlure he po" inlo a glaCs relOl l, and wirh a gra–
dualed lire draws off a very Alarp, vol'lile, minou! fpiril .
We obferveu
10
Par!
1.
Ihal fome metallie fubnances
have the propeny of decolllpofing fal ammoniac, and fe–
pmling irs volalil. alkali. MiolUm, wh,eh i, a
e.lxof
Icad, is one of rhol;, metallje fubnaoces. In thi! expe–
mntnl il d<compofes rhe f.1 amOlooiae, and f¿pames ils
volanle alkali: whal remai.'s io the relorl is a eombi–
ndlion of Ihe nllnium \Vilh the .cid of fal
ammoni~c,
\Vhich is well known10 be Ihef'me wilh Ihe marineacid:
and eonfcqueotly tho rdiJue of tbis opmrion is a fO il of
plumbulII
UJ'''t UIII,
The quanlily thereof is foul pounds eighl ounees.
Of
ulis he mixcs Iltree pounds with nioe or len pouods of
urine, tha! IldS 1I00d putrefying for !WO momh!, eupo–
wcd
10
tbe confinenee
oC
honey. Thefc he Olixes
L~