H
E
M
lhe
ernri~fc;
Cet
il io , owltiog
C\l1'o~ce;
plll ,:0111 all
r\\',oo it, ami kt IItC", kiodlc r,r.ldllally. l(.,il""
11t~
fire
(" as 10 m,lke thc crucible ver)'
r~o
hoto Wheo yOIl ob–
fe,,", that the flaltlc halh acqUlred a purplc or hlt,<ilh–
glwl colollr, lIocover lhe (r\ll.lole, antl "ip iolO it ao
iron \ltre,
1\1
exa01l0e whelhrr or 00 Ihe CC1pper be in
fllfinn ,,.,d·:r Ihe charcII"1dua.
If
you lind it is, mu–
,Ierale Ihe force
oC
lhe fire a lillle, and lel y01l1' crllcible
r"II.lill io Ihe fllrnace for a fcIV mioutes. Then take it
..111
aod lel it cool: yOIl will find yUllr copper of a gold
" ,Iollr, incrcafcd in weight a fOllnh, or pcrhaps a thinl
pal t, anJ yct very malleable.
The
IJtÍ! c.I"1IIi",,,.i,
is not lhe only Cub(lance with
wl,ich copper mal' be cOOl'erted ineo brafs, all other
OI CS containing zinc, lhe furnaee-c.l.lIl1ine· that fllblimcs
where fuch ores are \Volked, lutty, zinc io
fllb(l'l\e~,
01.1)'
be fllbaituted fur it, aod, likc il, will make "ely
nne br.lrs; but, in order lO [uc.:ceo, [undr)' l'recautions
are neeenary.
This procefs is a
Cort
of eemenlaliJn; for the calamine
doth not mele; onl)' Ihe zinc is convcrceJ inta npours,
and Ihen combines with the
corr.er. On Ihis the [ucceCs
oC
Ihe operation partl)' Jepends, as it is the means of the
copper's I'refen'ing its purit)' and maliedbility; becauCe
the otl'er metallic fubn anees that Ola)' be IInited with the
Oíe of zinc, or with tbe zinc ilCelf, not haviog the fame
vJlatility, eaonot be redueed tOvapours. lf you are ap–
prifcd that the calamine, or other ore of zinc ufed on
this oceafion, is contaminated \Vith a mixture of any o–
Iher metallic maner, you mun mingle luting eanh \Vilh
the eharcoal-duU and the malter containiog the zinc;
make il i"1O a niff pane \Vith water; of Ihis make a bed
at the botlom of your erllcible, and cam it hard down ;
lay the copper-plates thereon, cover lhem with eharcoal–
du!!, and then proeeed as before. By this meanI, \Vhen
the copper melts, it canOOl fall tO the bOltom of theccu–
eible, oor mix with the ore; but is borneup by the mix–
ture, and cannot combine wilh any thing but the zinc,
that rifes in vapours, and, paOing througb the lute, fixes
io the eopper.
LatÍ! Calaminarif,
or other ore of zinc, may be alfo
purified before it be ufed for making brafs; eCpeeially if
adulterated wil h lead ore, which is often Ihe cafe. For
this purpofe Ihe ore mlln be roaUed in a fire nrong e–
nough tO give a fmall degree of fufioo to the leaden mat–
ter; whieh
\ViII
thereby be reduced into larger, heavier,
and tougher malfes. The mon fubtile particles are dif–
fipaled io the torrefaaion, togelher wilh fome of the ca·
lamine. The calamine, on the contrary, is by roaniog
maoe more tender, liglmr, and much more friable. When
it is in this coooition, pllt it inlO a IVaflling tlay o\' fall
i
dip the tray in a velfel full of waler, and bruife Ihe mat–
ter il contaios. The \Vater will cmy oIT the lighte!!
powder, which is the calamine, and leave nothiog at the
boltom of lhe tray bU! the heavicfl fubn"ncc
i
that is,
lhe leaden mallCr, IVhich is to be rejcl'led as ufclef's.
The pówder of the calamine IVill fcttle at lhe bonomof
lhe veITd, where, afler pouring off the \Vater, it OIay be
fOllnd, and wCcu as above direélc.!.
In this optration the charcoal·uun {erves to prel'ent
bOlh the eopper and the zioc frolll beins nlcined: and
s
T
R
Y.
fol' tltis reafon, wheo you \Vork on a grea! quantity of
nt.\lel ials "t
onc~,
it is not neclnary to ufe fo much
ch,rcoal dnll, in proportion, as \Vhen you IVork bllt on
a fio:dl quantit:!; becaufe, the grealer the mafs of metal,
the Icfs calily \\'111 it calcine.
Tltollgh the CIIpper melts in this opecation, yet it is
fae fruOl "tiog oecelfary lo apply fueh a nrong fire as
copper
ulil~lIy
rClluires
10
mclt it, for the acceOion of the
zinc, on this occafion, communicates lOit a greal de–
gree of fufibility. The increafe of its weiílht is al[o
oIVing
t~
the .quantity of zinc combined with it. Cop–
per ¡cqulres Iltll another advantage by its alfociation IVilh
this [emi-metal; for it remaios longer in tite fire without
"Icining.
Br.liwell prepareo ought
lO
be malleable when colJ.
Hut in whate"er manocr
It
be oude, and \Vhatever pro–
ponion of zinc there be in it, it is cooUaotly fouod quile
unm.lleable
~'hen
red·hot.
Brafs mdted in a crucible, IVith
~
fieree heat, lakes
fire almon like zinc, and from its furface many while
Rowers aCcend, dancing aboul io Rakes Itke the
Rowers
of zinc. They are indeed the Rowers 01' zinc, and the
Rame of braCs urged by a flrong fire is no other than the
Rame of the zinc that is united \Vith the copper, aod then
burns. If brafs be thus kept long io fufion, it will lofe
almon all the zinc it contains.
It
will alfo lofe much
of its weight, aod il3 colour will be oear/y that of cop–
per,
lt
is lherefore neeelfary, towards performing thi.
operation aright, tO feize the momen! when the copper
is fuffi eiendy impregnated witb zinc, wlten it hath ac–
quired the mon weight and lhe finen colour, with rhe
Ica(l detriment to its Jm'lility, Ihat is poOible, and thal
innant ro put out the fire ; becaufc, if lhe copper be ler!
longer in fufion, it will only lofe the zinc already united
wirh il. Skill acqllired by much praaice, and an ac–
qllaineance \Vith tite particular calamine employed, are
neeelfary to guide Ihe artin furely through thisoperation
i
for thúe ate very eonfiderable dilferences between the
[undry ores of zinc. Some of themeontain lead, and in
otlters lhere is iron. When the[e heterogeneous metals
come tO be mixed \Vith tite copper,- tbey do iodeed aug–
ment its weighl, but they render it at the fame time pale,
and make it very harfll. Some calamines require to be
roaneel before they can be ufed for lhis purpofe, and in
the lorrefaaion emit vapours of a volatire alkali, fuc–
ec~ded
by vapours of a fulphureous fpiril: others ex–
hale no vapours while roaning, aod may be employed
\Vithout any antecedent preparation. T hefe differeot
qllalitics mul! evidently produce grea! differenees in tbe
operatiun.
Brafs mal' alfo be made, as prince's metal ¡nel other
irnilations of gold are aanally made, by ufiog zioe in
fllbllance, innead of the ores thal contain it. But the[e
cOlllpolitioos have not, \Vhen cold, the duaility of bra[s
prfpareclwilh
lapiJ cala/NinariJ,
becauf" zinc is feldom
pllre, or free from a mixture of
I~ad.
Perhaps alfo the
ddfcrent m:Ulner in which the zinc unires with the eopper
mal' cootribute
tu
Ihis variation.
To o!>viare litis incnnvcoienee, the zincmun be refineo
from'all alloy 01' Icad. The pr0l'eny of beiog inJilfo–
lublc by [ulphllr, which this
f~mi-mctal
polfeflcs, poinls
out