120
e
H
E
M
t\Viee its weight of ho! water; evaporate and erynallirc
as liefore. Repeat the Came opemion!illl he liquor wi l!
yield no more cryllals: it wil! then be very thick, and
gryes by the name of
tilo/ha
of
n¡/r~.
Earehs and 1I0nes that ha"e been impregnaten wilh a·
nimal or vegetable juiees fufceptible of putrcfaaion, and
ha"e beenlong cxpofed tOthe air, but !hdtered from Ihe
fun and rain, are thofe \Vhieh yicld the grcm lf qnaotilYof
oitre. BUI al! fOTls of carths aod 1I00es are not eqnally
lit to produce il. None is ever fou od in Hinls or fands
of a eryllallioe nature.
Sorne eanhs and 1I0nes abound
Co
with nilre, thal it ef–
/lorefees (pontaoeouOy on lheir furface, in Ihe form of a
crylblline down. This nitre may be eolleaed with
brooms, and aeeordingly has Ihe name of
Jnl/·p(lr~
! '
lJ.wP¡IIEt.
Some of Ihis fon is brough l from India.
The proee(s by whieh our falt.pme makers extraft
nitre in quanlities, out of rubbi!h aod nilrous earths, is
very nearly the fame with Ihat here fet do\Vn: (o Ihat we
!hall oot enter in10 a particular ae(ount of it. Wc !hall
only lake nOlice of one Ihing, whieh it is of fome eoofe ·
'luence to koow ; oamel)', that Ihere is 00 nil.rons eanh
\Vhieh does oot eontaio (ea·fall alfo. Tlwgreatdl quao·
lities of Ihis fall are to be IOllod id'·tho(e earths whieh
have been drenehed wilh urine or olher animal excre–
ments . Now, as Ihe rubbilh of old Iloufes in greal ci–
ties is io Ihis clafs, it comes 10 pafs, that when Ihe fa lt·
pelre workers evaporale a nilrous lixiviulIl drawo from
Ihat rubbifh, as foon as the evaporalion is brought 10 a
cenain piteh, a great nnny lillle eryllals of fea·falt
form in Ihe liquor, and fal! 10 Ihe bonom of lhe "ellel.
The ralt-pme workers in Franee cal! Ihefe f.line par–
lides
/h.
grail.,
and take great care 10 feparnte them
from lhe liquor, (whieh as long as il cominues hot keeps
tlle ( It-pelre difl'olvcd) before they fet il 10 eryllallife.
'I'his faa feems a linl. Gogular, eonGdering thal t'ea·f.1lt
dirYol'es in waler more eaGly than falt-petre, and ery–
ílallifes with more diffieulty.
lo order to difeover Ihe caule of this phenomenoo, we
mull reeollea, ftrll, Ihat water eao kcep but a deler.
minatequantity of any falt in folulion, and Ihat if waler
fully faluwed wilh a (alt be evaporaled, a quaotily uf
fal¡ will er)'l!allife in proponion tO lhe quaolity of Waler
el'aporalcd. Seeondly, thal lhofe falts whieh are the
mall foluble in warer, panielllarly thofe whieh run in
the air, will difl'olve in eold afld in boiling waler equal.
Iy; wherca, mueh ¡¡remr quanlilies of Ihe orher fAIIs
will difl'olve in hot and boiling waler lhan in eold water.
T hefe Ihings 'being admitted, when we know that fea–
fall is one of ¡he Grll fort, and fal¡.pelre of lhe fceond,
the reafon why fea- falt preeipitatcs in Ihe prcparalion of
[ah·pme appears at once. For,
When the folulion
off.lt'petreand fea fall comes tObe
evaporaled 10 fueh a degree that il eootains as mueh fea
falt asil poOibly eao, Ihis falt mull begin
10
eryllalhfe, aod
conlinue
10
do (o gradually as Ihe
evap~ration
advanees.
Hut
beeauf~
al Ihe fame lime it does nOl contain as mueh
falt· pelreas it eanhold, fccing il is eapable ofdifl'olving a
mueh gmtcr quaolity thereof when it is boiling hOI
Iha~
wheo it is cold, this lan named fal t wi!! not cryllallife
fo foon.
lf
the evaporillioo \Vere coolinued till Ihe caCe
s
T
R
Y.
oC
Ihe falt·petre came 10 be the fame with that of th!
fea falt, lhen the fah-petre alfo would begin 10 eryllallife
gradually in proponion tO the water evaporated, and the
, wo falts would canlinue cryllalliGng promi(euollny toge–
ther : but il is never carried (o far
j
nor is it ever necefl'ary;
for as Ihe water eools it beeomes more and more ioea–
pable of holdingiD folutionthe fame quantity of falt-petre
as wheo it wa's boiling hoto
And. lhen comes the very reverfe, wilh regaíd to the
eryllallrGog of Ihe IWO falts
j
for Ihen the falt.pelre
OIOOtS, and not Ihe fea-falt. The reafon of Ihis faa al·
fo is founded 00what has jull heen faid. The fea·falt,
of whieh cold water will difl'olve as much as boiliog wa–
ter, and whieh owed its cryllallifiog before only to lhe
evaporalinn, now ceafes to crynallife as fooo as Ihe eva-o
poration eeafes
j
while the falt.petre, whieh the water
kept difl'olved ooly beeaufe il was boiling hot, is foreed'
to eryllalliCe merely by the cooling of Ihe watér.
Wheo ¡he (olulion of
falt~ petre
has yielded as many
cryllals of lhal falt as it eaoyield by eoollOg. it is again
evaroraled, aod being then fuf!'ered to eool yields more
cryllals And Ihus Ihey continue evaporating and cry-
1I.lIiGng lill the liqllor will afford no more eryllals.
It
is plain, that as lhe fah'pme er)'lIallifes, the pro–
portioo of fca·falt 10 lhe difl'olving liquor inereafes; and
as a eenain quantilYof waler evapomes alfo during
the lime emrloyed in eryllalliGng Ihe falt·petre, a quao–
tityof
(~a·f.h,
proponioned tO the water· lo evaporaling,
mul! cryllallife in that time: and this is Ihe reafon why
falt1lclre is aduherated wilh a plixture of fea·falt.
It
hkewife foilows, thal Ihe lall cryllals of oitre, ob¡ained
froma folulion of fall petre and fea-fah , coolain mueh
more fea·f.1It than the ¡irll.
rrolO afl Ihat has been faid coneeroing Ihe eryllallifa'–
tion of fah-petre and lea
·f.ll,it is eafy to deduce the
proper way of purifying ¡he lormer of th& two falts
from a mixlore of the laner. Fur Ihis purporc the falt–
pelre
10
be refioed need only be dlil'oll'ed in fa ir water.
T he proponion helwten the tWO (¡!lIS in Ihis fceond fo–
Imion is I'rry difr.rent fromwha! il was in the former;
for il eoritains no more fea·falt Ihan whal had eryllal–
lired
al~ng
with lhe fah -pme under fal'ollr of the evapo–
ration, Ihe rcll having been left difl'oll'ed io the liq'uor
Ihal rcfufed 10 yicld aoy more nitrous eryllals.
As there is lherefore a mueh gremr quantity of fah–
pelre Ihan 'of fea-fall in this feeond
folu~ion,
il is eafy
10
cvapome il to fueh a degree Iha! a grea, deal of fah–
pelre nlall eryllallife, whilt much more of Ihe water
mull neeefl'arily be evaporaled before any of the fea· fal:
\ViII erylLdlife.
However, Ihe falt.petre is nOl yet eOlirelyfreed from
all mixture of fea-fah by lhis fidl purifiealioo; for lhe
the cr)'lIals obtained from this liquor, io whieh fea-falt
is dilfolved, are lIill rnerulled, aod, as it were, iofcaed
therewith: henee it comes, Ihat, 10 refine Ihe fah·petre
thoroughly, Ihefe cryUaififalions mull be repeated four.
or Gvc limes.
Thc f,lt-pelre meo commonly cooleot Ihemfel'es wilh
cryllalfiGng it lhriee, and eall Ihe product fah-petre of
the firn, fceond. or third nlOOI, aecording 10 Ihe nllm–
ber of cryllallifations it
ha~
uodergone. Ilut lheir be!!
refined